No, Brisela will not prevent your opponent from casting Volarden Pariah for its madness cost.
"Mana cost", and by extension "converted mana cost" specifically refers to the cost printed at the top of the card. The relevant rules are here:
202.1. A card’s mana cost is indicated by mana symbols near the top of the card. (See rule 107.4.) [...]
202.3. The converted mana cost of an object is a number equal to the total amount of mana in its mana cost, regardless of color.
So, Volarden Pariah always has a mana cost of {3}{B}{B}, and a converted mana cost of 5.